Design and simulation of gas solid vortex reactor for process intensification of selected reactions

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Solids velocity fields in a cold-flow Gas-Solid Vortex Reactor

In a Gas–Solid Vortex Reactor (GSVR), also referred to as a Rotating Fluidized Bed in Static Geometry, a fluidized bed is generated in a centrifugal field by introducing the gas via tangential inlet slots to the reactor chamber. Better heat and mass transfer are observed, making this a promising reactor type for Process Intensification. Developing GSVRs on industrial scale requires, amongst other, a good insight and understanding of the hydrodynamics of the granular flow. In the present work experiments are performed over a wide range of operating conditions in a cold flow pilot-scale set-up. The set-up has a diameter of 0.54 m, a length of 0.1 m and 36 tangential inlet slots of 2 mm. Different materials with solids density between 950–1800 kg/m3 and particle diameters of 1–2 mm, at varying gas injection velocities from 55 to 110 m/s are tested between minimum and maximum solids capacities. All these operating conditions are used to follow the change of granular flow by performing PIV. The rotating fluidized bed can change from a smoothly rotating, densely fluidized bed to a highly bubbling rotating fluidized bed depending on the operating conditions. Bubbling diminishes with increasing solids density and particle diameter. Experimental measurements of azimuthal particle velocity fields in a GSVR are for the first time reported. Azimuthal solids velocity is found to decrease with higher solids density and larger particle diameter. The critical minimum fluidization velocity, that is the minimum velocity at which the complete bed is fluidized, is calculated and the centrifugal bed behavior is mapped in terms of a dimensionless radial gas velocity and a dimensionless particle diameter, as conventionally done for gravitational beds

Experimentally validated numerical study of gas-solid vortex unit hydrodynamics

AbstractA three-dimensional numerical analysis of the flow in a Gas-Solid Vortex Unit (GSVU) is carried out. The numerical model is first validated by comparing the bed pressure drop and solids velocity with experimental data. Next, the influence of gas flow rate, solids density, and particle diameter on the pressure drop, solids velocity, bed void fraction and slip velocity between the two phases is studied. A stable, solids bed is achieved for the entire range of gas flow rates tested (0.1–0.6Nm3/s). No particle entrainment is observed when varying the solid density (1800–450kg/m3) or the particle diameter (2–0.5mm). A shift to bubbling fluidization regime is observed for small particle diameters (0.5mm). The observed changes in the GSVU flow patterns are discussed by analyzing the changes in the cumulative centrifugal to drag force ratio over the bed

Quo vadis multiscale modeling in reaction engineering? A perspective

This work reports the results of a perspective workshop held in summer 2021 discussing the current status and future needs for multiscale modeling in reaction engineering. This research topic is one of the most challenging and likewise most interdisciplinary in the chemical engineering community, today. Although it is progressing fast in terms of methods development, it is only slowly applied by most reaction engineers. Therefore, this perspective is aimed to promote this field and facilitate research and a common understanding. It involves the following areas: (1) reactors and cells with surface changes focusing on Density Functional Theory and Monte-Carlo simulations; (2) hierarchically-based microkinetic analysis of heterogeneous catalytic processes including structure sensitivity, microkinetic mechanism development, and parameter estimation; (3) coupling first-principles kinetic models and CFD simulations of catalytic reactors covering chemistry acceleration strategies and surrogate models; and finally (4) catalyst-reactor-plant systems with details on linking CFD with plant simulations, respectively. It therefore highlights recent achievements, challenges, and future needs for fueling this urgent research topic in reaction engineering